are these waterproof?

No! In fact they have tiny ventilation holes in the bottom… You would need to use a thick batter, liquid would just leak out

Does bake time or temp vary from regular loaf pans?

Bake time is usually about right...do bake allot of banana breads which I place on tray for baking at 350 with my recipe and done at approximately right time for this recipe. Always good to keep an eye on baked goods when using a new recipe...ovens temperatures sometimes make a difference in results. Very pleased with these paper baking pans...freeze and use for gift sharing later.

I'm not exactly you sure what you mean by "comfortable." They are sturdy and are exactly the type of pan that my local bakery uses for their pound cakes. I had to return mine because they were the wrong size. But look to be good quality and sturdy.

can you make brownies in these?

I used spay pan and made fruitcakes in these. I also made different breads. I would say absolutely you ca make brownies in these

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